Nihonium

    group 13 · period 7 · p-block · unknown, probably transition metal

    Identity

    Name and symbol
    Nihonium, Nh
    Atomic number
    113 protons
    Position
    group 13 · period 7 · p-block · unknown, probably transition metal
    CAS number
    54084-70-7

    Atomic structure

    Atomic mass
    286 u
    Electron configuration
    1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁶ 5s² 4d¹⁰ 5p⁶ 6s² 4f¹⁴ 5d¹⁰ 6p⁶ 7s² 5f¹⁴ 6d¹⁰ 7p¹
    [Rn] 5f¹⁴ 6d¹⁰ 7s² 7p¹(predicted)
    Electrons per shell
    2, 8, 18, 32, 32, 18, 3
    Valence electrons
    3 outer shell
    nuclidehalf-lifedecay
    289Nh30 s [Estimated]α ?; SF ?
    287Nh20 s [Estimated]α ?; SF ?
    288Nh20 s [Estimated]α ?; SF ?
    286Nh12 sα=100%
    no stable isotope; the longest-lived nuclides

    Physical properties

    State at room temperature
    Expected to be a Solid
    Melting point
    700 K (426.85 °C)
    Boiling point
    1,430 K (1,156.85 °C)
    Density
    not in sources
    Appearance
    not in sources
    Thermal conductivity
    not in sources
    Electrical resistivity
    not in sources
    Electrical conductivity
    not in sources
    Crystal structure
    hexagonal close-packed
    Molar heat capacity
    not in sources

    Chemical properties

    Oxidation states
    not in sources
    Electronegativity
    not in sources
    Ionisation energy
    not in sources
    Electron affinity
    not in sources
    Atomic radius
    not in sources
    Ionic radius
    not in sources
    Reactivity
    A group 13 transactinide studied only by adsorption of single atoms: early JINR runs (2010 to 2017) found it unexpectedly retained on PTFE, and a 2024 GSI experiment measured its adsorption on silica, less reactive than thallium but more than copernicium and flerovium, owing to relativistic stabilization of the 7p1/2 shell.
    with water
    Not known; no experiment has been reported.
    with oxygen, air
    Not known; no experiment has been reported.
    with acids
    Not known; no experiment has been reported.
    with halogens
    Not known; no experiment has been reported.
    Typical compounds
    not in sources

    Occurrence, production and use

    Crustal abundance
    Not Applicable
    Oceanic abundance
    Not Applicable
    Occurrence and sources
    • synthetic only zinc ions on a bismuth target at RIKEN; also reached via decay of moscovium made from americium-243 and calcium-48
    Extraction, production
    not in sources
    Uses

    Since only a few atoms of nihonium have ever been produced, it currently has no uses outside of basic scientific research.

    Safety, toxicity
    not in sources

    Discovery and name

    Discovered by
    Riken (Japan, first undisputed claim 2004)JINR (Russia) and Livermore (US, first announcement 2003)
    Discovered
    2004
    First isolated
    not in sources
    Named by
    not in sources
    Origin of the name
    After Japan (Nihon in Japanese)

    Nihonium does not occur naturally in the Earth’s crust. The name nihonium and the symbol Nh are the accepted ones for element 113. Nihon is one of the two ways to say “Japan” in Japanese and means “the land of the Rising Sun.” It is the first element to have been discovered in an Asian country [665], [666], [667].

    The synthesis of nihonium was first announced in 2004. The Joint Institute for Nuclear Research (JINR) and the Lawrence Livermore National Laboratory were able to produce two super-heavy elements by bombarding a rotating 243Am disc with an ion beam of 48Ca in a U-400 cyclotron. During the reaction, isotopes of moscovium, previously known as ununpentium, were synthesized and decayed in a tenth of a second to nihonium, which then decayed to roentgenium. Because the atoms of moscovium only existed for a tenth of a second, radiochemical proof was needed to support its syntheses. A Swiss scientist at the Paul Scherrer Institute (PSI) performed the radiochemical experiment by analyzing a copper plate that had been placed behind the 243Am disc in the cyclotron. This copper plate collected all moscovium atoms that were synthesized and was processed through liquid chromatography techniques that yielded five times more moscovium atoms than produced by fusion alone. The direct synthesis of nihonium was announced later that year by a team of Japanese scientists from the Cyclotron Center of the RIKEN Research Institute. These scientists bombarded atoms of 209Bi with a beam of 70Zn in a RIKEN heavy-ion linear accelerator (RILAC), shown in Fig. IUPAC.113.1, and gas-filled recoil ion separator (GARIS), shown in Fig. IUPAC.113.2. Nihonium has no known isotopic applications aside from scientific research.

    Conventions

    Valence electrons are counted by the usual convention: the outer shell for s- and p-block elements, ns and (n-1)d for the d-block, ns, (n-1)d and (n-2)f for the f-block. Lanthanides and actinides are placed in the f-block with no group number. Electrical conductivity is the reciprocal of the printed resistivity. Ionic radii are Shannon effective radii, six-coordinate unless noted. Where a field reads “not in sources” the value was not found; it is a gap, not a zero. Regulatory limits are the published values and change often, so check the standard in force at your site and the numbers written into your own permit before you design to them.

    Data

    Element records, isotopes, radii and the descriptive text come from PubChem (NCBI), the Los Alamos National Laboratory periodic table, IUPAC CIAAW and the IAEA Atomic Mass Data Center. Appearance, thermal conductivity, electrical resistivity, crystal structure, discovery and the origin of each name come from Wikipedia and Periodic-Table-JSON, used under CC BY-SA 4.0. Hazard classifications come from the ECHA C&L inventory via PubChem. Ionic radii follow R. D. Shannon (1976). The water chapters cite their own sources at the foot of each entry, and are written to the level of Snoeyink and Jenkins, Stumm and Morgan, MWH's Water Treatment and Metcalf and Eddy.