Nihonium
not relevantNihonium has no water story: only a few atoms have ever been made, so it has no measurable occurrence in water, no guideline and no treatment role.
1 · Identity
- Symbol, number
- Nh, 113
- Oxidation states in water
- none listed (book entry)
- Note
- Identity from the book entry; nothing measured in water.
Sources
Identity
- Name and symbol
- Nihonium, Nh
- Atomic number
- 113 protons
- Position
- group 13 · period 7 · p-block · unknown, probably transition metal
- CAS number
- 54084-70-7
Atomic structure
- Atomic mass
- 286 u
- Electron configuration
- 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁶ 5s² 4d¹⁰ 5p⁶ 6s² 4f¹⁴ 5d¹⁰ 6p⁶ 7s² 5f¹⁴ 6d¹⁰ 7p¹
[Rn] 5f¹⁴ 6d¹⁰ 7s² 7p¹(predicted) - Electrons per shell
- 2, 8, 18, 32, 32, 18, 3
- Valence electrons
- 3 outer shell
| nuclide | half-life | decay |
|---|---|---|
| 289Nh | 30 s [Estimated] | α ?; SF ? |
| 287Nh | 20 s [Estimated] | α ?; SF ? |
| 288Nh | 20 s [Estimated] | α ?; SF ? |
| 286Nh | 12 s | α=100% |
Physical properties
- State at room temperature
- Expected to be a Solid
- Melting point
- 700 K (426.85 °C)
- Boiling point
- 1,430 K (1,156.85 °C)
- Density
- not in sources
- Appearance
- not in sources
- Thermal conductivity
- not in sources
- Electrical resistivity
- not in sources
- Electrical conductivity
- not in sources
- Crystal structure
- hexagonal close-packed
- Molar heat capacity
- not in sources
Chemical properties
- Oxidation states
- not in sources
- Electronegativity
- not in sources
- Ionisation energy
- not in sources
- Electron affinity
- not in sources
- Atomic radius
- not in sources
- Ionic radius
- not in sources
- Reactivity
- A group 13 transactinide studied only by adsorption of single atoms: early JINR runs (2010 to 2017) found it unexpectedly retained on PTFE, and a 2024 GSI experiment measured its adsorption on silica, less reactive than thallium but more than copernicium and flerovium, owing to relativistic stabilization of the 7p1/2 shell.
- with water
- Not known; no experiment has been reported.
- with oxygen, air
- Not known; no experiment has been reported.
- with acids
- Not known; no experiment has been reported.
- with halogens
- Not known; no experiment has been reported.
- Typical compounds
- not in sources
Occurrence, production and use
- Crustal abundance
- Not Applicable
- Oceanic abundance
- Not Applicable
- Occurrence and sources
- synthetic only zinc ions on a bismuth target at RIKEN; also reached via decay of moscovium made from americium-243 and calcium-48
- Extraction, production
- not in sources
- Uses
Since only a few atoms of nihonium have ever been produced, it currently has no uses outside of basic scientific research.
- Safety, toxicity
- not in sources
Discovery and name
- Discovered by
- Riken (Japan, first undisputed claim 2004)JINR (Russia) and Livermore (US, first announcement 2003)
- Discovered
- 2004
- First isolated
- not in sources
- Named by
- not in sources
- Origin of the name
- After Japan (Nihon in Japanese)
Nihonium does not occur naturally in the Earth’s crust. The name nihonium and the symbol Nh are the accepted ones for element 113. Nihon is one of the two ways to say “Japan” in Japanese and means “the land of the Rising Sun.” It is the first element to have been discovered in an Asian country [665], [666], [667].
The synthesis of nihonium was first announced in 2004. The Joint Institute for Nuclear Research (JINR) and the Lawrence Livermore National Laboratory were able to produce two super-heavy elements by bombarding a rotating 243Am disc with an ion beam of 48Ca in a U-400 cyclotron. During the reaction, isotopes of moscovium, previously known as ununpentium, were synthesized and decayed in a tenth of a second to nihonium, which then decayed to roentgenium. Because the atoms of moscovium only existed for a tenth of a second, radiochemical proof was needed to support its syntheses. A Swiss scientist at the Paul Scherrer Institute (PSI) performed the radiochemical experiment by analyzing a copper plate that had been placed behind the 243Am disc in the cyclotron. This copper plate collected all moscovium atoms that were synthesized and was processed through liquid chromatography techniques that yielded five times more moscovium atoms than produced by fusion alone. The direct synthesis of nihonium was announced later that year by a team of Japanese scientists from the Cyclotron Center of the RIKEN Research Institute. These scientists bombarded atoms of 209Bi with a beam of 70Zn in a RIKEN heavy-ion linear accelerator (RILAC), shown in Fig. IUPAC.113.1, and gas-filled recoil ion separator (GARIS), shown in Fig. IUPAC.113.2. Nihonium has no known isotopic applications aside from scientific research.
Conventions
Valence electrons are counted by the usual convention: the outer shell for s- and p-block elements, ns and (n-1)d for the d-block, ns, (n-1)d and (n-2)f for the f-block. Lanthanides and actinides are placed in the f-block with no group number. Electrical conductivity is the reciprocal of the printed resistivity. Ionic radii are Shannon effective radii, six-coordinate unless noted. Where a field reads “not in sources” the value was not found; it is a gap, not a zero. Regulatory limits are the published values and change often, so check the standard in force at your site and the numbers written into your own permit before you design to them.
Data
Element records, isotopes, radii and the descriptive text come from PubChem (NCBI), the Los Alamos National Laboratory periodic table, IUPAC CIAAW and the IAEA Atomic Mass Data Center. Appearance, thermal conductivity, electrical resistivity, crystal structure, discovery and the origin of each name come from Wikipedia and Periodic-Table-JSON, used under CC BY-SA 4.0. Hazard classifications come from the ECHA C&L inventory via PubChem. Ionic radii follow R. D. Shannon (1976). The water chapters cite their own sources at the foot of each entry, and are written to the level of Snoeyink and Jenkins, Stumm and Morgan, MWH's Water Treatment and Metcalf and Eddy.